Thermodynamics
Thermodynamics ->> FIRST LAW The first law of thermodynamics gives a precise definition of heat, another commonly used concept. When an object is brought into contact with a relatively colder object, a process takes place that brings about an equalization of temperatures of the two objects. To explain this phenomenon, 18th-century scientists hypothesized that a substance more abundant at higher temperature flowed toward the region at a lower temperature. This hypothetical substance, called “caloric,” was thought to be a fluid capable of moving through material media. The first law of thermodynamics instead identifies caloric, or heat, as a form of energy. It can be converted into mechanical work, and it can be stored, but is not a material substance. Heat, measured originally in terms of a unit called the calorie, and work and energy, measured in ergs, were shown by experiment to be totally equivalent. One calorie is equivalent to 4.186 × 107 ergs, or 4.186 joules. The first law,